Trapp C.A. Student's solutions manual to accompany Atkins' physical chemistry / C.A.Trapp, M.P.Cady, C.Giunta. - 9th ed. - Oxford; New-York: Oxford University Press, 2010. - viii, 599 p. - ISBN 978-0-19-958397-3  Место хранения:   054 | Международный томографический центр CO РАН | Новосибирск

Оглавление / Contents

Fundamentals .................................................... 1 Exercises ....................................................... 1 F.l Atoms .................................................... 1 F.2 Molecules ................................................ 2 F.3 Bulk matter .............................................. 4 F.4 Energy ................................................... 6 F.5 The relationship between molecular and bulk properties ... 7 F.6 The electromagnetic field ................................ 8 F.7 Units .................................................... 8 Part 1 Equilibrium ............................................ 11 1 The properties of gases ..................................... 13 Answers to discussion questions ............................. 13 Solutions to exercises ...................................... 14 Solutions to problems ....................................... 23 Solutions to numerical problems .......................... 23 Solutions to theoretical problems ........................ 28 Solutions to applications ................................ 31 2 The first law ............................................... 34 Answers to discussion questions ............................. 34 Solutions to exercises ...................................... 35 Solutions to problems ....................................... 46 Solutions to numerical problems .......................... 46 Solutions to theoretical problems ........................ 54 Solutions to applications ................................ 61 3 The second law .............................................. 62 Answers to discussion questions ............................. 62 Solutions to exercises ...................................... 63 Solutions to problems ....................................... 70 Solutions to numerical problems .......................... 70 Solutions to theoretical problems ........................ 79 Solutions to applications ................................ 84 4 Physical transformations of pure substances ................. 88 Answers to discussion questions ............................. 88 Solutions to exercises ...................................... 89 Solutions to problems ....................................... 94 Solutions to numerical problems .......................... 94 Solutions to theoretical problems ........................ 97 Solutions to applications ............................... 100 5 Simple mixtures ............................................ 102 Answers to discussion questions ............................ 102 Solutions to exercises ..................................... 104 Solutions to problems ...................................... 120 Solutions to numerical problems ......................... 120 Solutions to theoretical problems ....................... 130 Solutions to applications ............................... 135 6 Chemical equilibrium ....................................... 141 Answers to discussion questions ............................ 141 Solutions to exercises ..................................... 143 Solutions to problems ...................................... 154 Solutions to numerical problems ......................... 154 Solutions to theoretical problems ....................... 163 Solutions to applications: biology, environmental science, and chemical engineering ....................... 165 PART 2 Structure ............................................. 169 7 Quantum theory: introduction and principles ................ 171 Answers to discussion questions ............................ 171 Solutions to exercises ..................................... 172 Solutions to problems ...................................... 178 Solutions to numerical problems ......................... 178 Solutions to theoretical problems ....................... 181 Solutions to applications: nanoscience, environmental science, and astrophysics ............................... 191 8 Quantum theory: techniques and applications ................ 194 Answers to discussion questions ............................ 194 Solutions to exercises ..................................... 195 Solutions to problems ...................................... 203 Solutions to numerical problems ......................... 203 Solutions to theoretical problems ....................... 205 Solutions to applications ............................... 216 9 Atomic structure and spectra ............................... 220 Answers to discussion questions ............................ 220 Solutions to exercises ..................................... 221 Solutions to problems ...................................... 228 Solutions to numerical problems ......................... 228 Solutions to theoretical problems ....................... 232 Solutions to applications ............................... 239 10 Molecular structure ........................................ 243 Answers to discussion questions ............................ 243 Solutions to exercises ..................................... 245 Solutions to problems ...................................... 253 Solutions to numerical problems ......................... 253 Solutions to theoretical problems ....................... 265 Solutions to applications ............................... 268 11 Molecular symmetry ......................................... 271 Answers to discussion questions ............................ 271 Solutions to exercises ..................................... 275 Solutions to problems ...................................... 279 Solutions to numerical problems ......................... 279 Solutions to applications: astrophysics and biology ..... 287 12 Molecular spectroscopy 1: rotational and vibrational spectra .................................................... 289 Answers to discussion questions ............................ 289 Solutions to exercises ..................................... 290 Solutions to problems ...................................... 300 Solutions to numerical problems ......................... 300 Solutions to theoretical problems ....................... 308 Solutions to applications ............................... 312 13 Molecular spectroscopy 2: electronic transitions ........... 318 Answers to discussion questions ............................ 318 Solutions to exercises ..................................... 320 Solutions to problems ...................................... 328 Solutions to numerical problems ......................... 328 Solutions to theoretical problems ....................... 334 Solutions to applications: biochemistry, environmental science, and astrophysics ............................... 336 14 Molecular spectroscopy 3: magnetic resonance ............... 339 Answers to discussion questions ............................ 339 Solutions to exercises ..................................... 340 Solutions to problems ...................................... 349 Solutions to numerical problems ......................... 349 Solutions to theoretical problems ....................... 353 Solutions to applications ............................... 355 15 Statistical thermodynamics 1: the concepts ................. 357 Answers to discussion questions ............................ 357 Solutions to exercises ..................................... 358 Solutions to problems ...................................... 369 Solutions to numerical problems ......................... 369 Solutions to theoretical problems ....................... 375 Solutions to applications ............................... 379 16 Statistical thermodynamics 2: applications ................. 380 Answers to discussion questions ............................ 380 Solutions to exercises ..................................... 380 Solutions to problems ...................................... 388 Solutions to numerical problems ......................... 388 Solutions to theoretical problems ....................... 397 Solutions to applications ............................... 404 17 Molecular interactions ..................................... 407 Answers to discussion questions ............................ 407 Solutions to exercises ..................................... 410 Solutions to problems ...................................... 416 Solutions to numerical problems ......................... 416 Solutions to theoretical problems ....................... 422 Solutions to applications: biochemistry ................. 427 18 Materials 1: macromolecules and self-assembly .............. 430 Answers to discussion questions ............................ 430 Solutions to exercises ..................................... 431 Solutions to problems ...................................... 436 Solutions to numerical problems ......................... 436 Solutions to theoretical problems ....................... 441 Solutions to applications: biochemistry and technology .............................................. 445 19 Materials 2: solids ........................................ 455 Answers to discussion questions ............................ 455 Solutions to exercises ..................................... 458 Solutions to problems ...................................... 468 Solutions to numerical problems ......................... 468 Solutions to theoretical problems ....................... 475 Solutions to applications: biochemistry and nanoscience ............................................. 481 Part 3 Change ................................................ 485 20 Molecules in motion ........................................ 487 Answers to discussion questions ............................ 487 Solutions to exercises ..................................... 489 Solutions to problems ...................................... 503 Solutions to numerical problems ......................... 503 Solutions to theoretical problems ....................... 508 Solutions to applications: astrophysics and biochemistry ............................................ 512 21 The rates of chemical reactions ............................ 515 Answers to discussion questions ............................ 515 Solutions to exercises ..................................... 518 Solutions to problems ...................................... 528 Solutions to numerical problems ......................... 528 Solutions to theoretical problems ....................... 536 Solutions to applications ............................... 541 22 Reaction dynamics .......................................... 544 Answers to discussion questions ............................ 544 Solutions to exercises ..................................... 545 Solutions to problems ...................................... 555 Solutions to numerical problems ......................... 555 Solutions to theoretical problems ....................... 561 Solutions to applications ............................... 568 23 Catalysis .................................................. 571 Answers to discussion questions ............................ 571 Solutions to exercises ..................................... 573 Solutions to problems ...................................... 578 Solutions to numerical problems ......................... 578 Solutions to theoretical problems ....................... 588 Solutions to applications: chemical engineering and environmental science ................................... 594