Kuhl O. Phosphoros-31 NMR Spectroscopy (Вerlin; Heidelberg, 2008). - ОГЛАВЛЕНИЕ / CONTENTS
Навигация

Архив выставки новых поступлений | Отечественные поступления | Иностранные поступления | Сиглы
ОбложкаKühl O. Phosphorus-31 NMR Spectroscopy. - Вerlin; Heidelberg: Springer, 2008. - xiv, 131 p. - ISBN 978-3-540-79117-1
 

Оглавление / Contents
 
1. Short Review of NMR Theory ................................... 1

   1.1. Origin of the Spectrum .................................. 1
   1.2. Coupling to other Nuclei ................................ 5
   Bibliography ................................................. 6
   
2. The Range of Chemical Shifts, Coupling Constants,
   and What Influences Each ..................................... 7

   2.1. Chemical Shift Values ................................... 9
   2.2. Coupling Constants ..................................... 15
        2.2.1. Coupling to Hydrogen ............................ 16
        2.2.2. Coupling to Carbon .............................. 18
        2.2.3. Coupling to Phosphorus .......................... 21
        2.2.4. Coupling to Metals .............................. 22
   Bibliography ................................................ 23

3. Oxidation State from P(-III) over P(0) to P(+V) ............. 25

   Bibliography ................................................ 29

4. λ5-Phosphanes ............................................... 31

   Bibliography ................................................ 35

5. λ3-Phosphanes ............................................... 37

   5.1. Phosphorus Element Single Bonds ........................ 37
        Box Story: Electronic and Steric Properties of
        Phosphanes and Phosphites .............................. 44
   5.2. Phosphorus Carbon Multiple Bonds ....................... 47
   5.3. Phosphorus Phosphorus Bonds ............................ 59
        5.3.1. Diphosphanes .................................... 60
        5.3.2. Diphosphenes .................................... 65
   Bibliography ................................................ 68

6. Main Group Compounds ........................................ 71

   6.1. As Lewis Base .......................................... 71
   6.2. As Lewis Acid P(I), P(III), and P(V) ................... 75
   Bibliography ................................................ 81

7. Transition Metal Complexes .................................. 83

   7.1. Phosphanes ............................................. 83
   7.2. Chelate Phosphanes (Influence of Ring Size) ............ 87
   7.3. Phosphides (Terminal and Bridging) ..................... 89
   7.4. Phosphinidines (Terminal and Bridging) ................ 101
   7.5. Phosphaacetylene Complexes ............................ 112
   7.6. Agostic M-P-H Interactions ............................ 115
   7.7. Naked Phosphorus ...................................... 117
   Box Story: Isolobal Theory ................................. 125
   Bibliography ............................................... 126

Index ......................................................... 129


Архив выставки новых поступлений | Отечественные поступления | Иностранные поступления | Сиглы
 

[О библиотеке | Академгородок | Новости | Выставки | Ресурсы | Библиография | Партнеры | ИнфоЛоция | Поиск]
  © 1997–2024 Отделение ГПНТБ СО РАН  

Документ изменен: Wed Feb 27 14:20:02 2019. Размер: 6,399 bytes.
Посещение N 1822 c 04.08.2009